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Evaluation of a lab-scale ionic liquid synthesis using life cycle assessment
DOI: 10.1039/D5GC06385J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Rhea Mathew, Sirui Chen, Agnieszka Brandt-Talbot, Jacqueline S. Edge, Tom WeltonLife cycle assessment of a lab-scale ionic liquid synthesis: project methodology flowchart, single damage score comparison, and recommendations.
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Biodegradable polyurethane non-tackifier pressure-sensitive adhesive derived from cashew nut shells
DOI: 10.1039/D5GC05627F, PaperSeo Jeong Hur, Yongha Jeon, Haemin Jeong, Jimin Shim, Jihoon Shin, Kwon Yong Choi, U Hyeok Choi, Hee Joong Kim
A cardanol-derived polyurethane pressure-sensitive adhesive exhibits strong adhesion without tackifiers and rapid degradability under mild conditions, enabled by unsaturated alkyl chains.
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Ionic atmosphere and temperature field–promoted dissociation and phase reconstruction of bastnaesite
DOI: 10.1039/D5GC05704C, PaperQionghua Xie, Yifan Hao, Guocheng Yao, Cong Wang, Liangshi Wang
The SO42− ionic atmosphere and thermal-field phase reconstruction enable the green and efficient recovery of both rare earth and fluorine resources.
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PET-upcycled and biobased hyperbranched polyesters for self-healable and flame-retardant powder coatings
DOI: 10.1039/D6GC00220J, PaperSong Gu, Jingjing Du, Yaqiong Zhang, Wangcheng Liu, Gustavo de Figueiredo Brito, Yiding Cao, Baoming Zhao, Jinwen Zhang
Upcycled PET-derived phosphorus-containing hyperbranched polyesters, combined with a biobased resveratrol epoxy, enable VOC-free powder coatings with self-healing, fire safety, and practical performance.
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Synchronous recognition of P–intermediates and nucleophiles empowers diversified trivalent phosphorus synthesis
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC00555A, PaperXue Liu, Jingcheng Hu, Chengbiao Zhu, Dake Wang, Jia Yan, Jinyu Wang, Zhenwei Wei, Yong Yuan, Hong Yi, Aiwen Lei
Trivalent phosphines bearing P–X bonds are valuable intermediates, antioxidants, ligands, and functional agents, yet their sustainable and selective synthesis remains challenging. Here we present a synchronous identification strategy for P-intermediates...
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DOI: 10.1039/D6GC00555A, PaperXue Liu, Jingcheng Hu, Chengbiao Zhu, Dake Wang, Jia Yan, Jinyu Wang, Zhenwei Wei, Yong Yuan, Hong Yi, Aiwen Lei
Trivalent phosphines bearing P–X bonds are valuable intermediates, antioxidants, ligands, and functional agents, yet their sustainable and selective synthesis remains challenging. Here we present a synchronous identification strategy for P-intermediates...
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Machine Learning Framework to Predict Glass Transition Temperature in Natural Deep Eutectic Solvents: A Step toward Green Functional Materials
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC01009A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Durbek Usmanov, Priyanka Yadav, Gerardo M. Casanola-Martin, Akshat Mallya, Seyedehelham Shirvanihosseini, Allison Hubel, Bakhtiyor Rasulev
Natural Deep Eutectic Solvents (NADES) are a promising class of sustainable and environmentally-safe solvents with highly tunable physicochemical properties, including the glass transition temperature, which is critical for their functional...
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DOI: 10.1039/D6GC01009A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Durbek Usmanov, Priyanka Yadav, Gerardo M. Casanola-Martin, Akshat Mallya, Seyedehelham Shirvanihosseini, Allison Hubel, Bakhtiyor RasulevNatural Deep Eutectic Solvents (NADES) are a promising class of sustainable and environmentally-safe solvents with highly tunable physicochemical properties, including the glass transition temperature, which is critical for their functional...
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CO₂-Enabled Electrochemical Selective Deuterodefluorination of β,γ-Unsaturated α,α-Difluoroesters with Tunable Alkene Deuteration
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC01929C, PaperYuhang Dong, Ping Lv, Yingying Chen, Yanni Yue, Xiaoli Bu, Hong-Ping Deng, Mengtao Ma, Fei Xue
Recent advances in deuteration, including C-F bond deuterodefluorination and alkene reductive deuteration, have enabled site-selective isotope labeling of bioactive molecules and functional materials. Nevertheless, most methods rely on precious metals,...
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DOI: 10.1039/D6GC01929C, PaperYuhang Dong, Ping Lv, Yingying Chen, Yanni Yue, Xiaoli Bu, Hong-Ping Deng, Mengtao Ma, Fei Xue
Recent advances in deuteration, including C-F bond deuterodefluorination and alkene reductive deuteration, have enabled site-selective isotope labeling of bioactive molecules and functional materials. Nevertheless, most methods rely on precious metals,...
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Non-decarboxylative functionalization of free carboxylic acids: Strategies for C–O bond formation via photo- and electrochemical approaches
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC00661B, Critical ReviewBinbin Huang
Carboxylic acids are among the most readily available, bench-stable, and cost-effective building blocks in organic chemistry. However, the low reactivity of free carboxyl group in both electrophilic and nucleophilic transformations...
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DOI: 10.1039/D6GC00661B, Critical ReviewBinbin Huang
Carboxylic acids are among the most readily available, bench-stable, and cost-effective building blocks in organic chemistry. However, the low reactivity of free carboxyl group in both electrophilic and nucleophilic transformations...
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Electrochemical Nitrate-to-Ammonia Conversion over a Broad Concentration Range via a Hollow Co3O4/CuO Catalyst
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC00484A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Li Yao, Shao YE, Zhe Li, Mingjie Tuo, Yibin Cui, Zhenbin Wang, Zhenhua Xie, Wenlei Zhu, Bo Shen
Widespread nitrate contamination in water challenges both aquatic ecosystems and drinking water safety, and the electrocatalytic nitrate reduction to ammonia (eNRA) presents a promising sustainable way to convert pollutants to...
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DOI: 10.1039/D6GC00484A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Li Yao, Shao YE, Zhe Li, Mingjie Tuo, Yibin Cui, Zhenbin Wang, Zhenhua Xie, Wenlei Zhu, Bo ShenWidespread nitrate contamination in water challenges both aquatic ecosystems and drinking water safety, and the electrocatalytic nitrate reduction to ammonia (eNRA) presents a promising sustainable way to convert pollutants to...
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Visible Light Induced 6π Electrocyclization: Divergent Synthesis of Seven Membered Ring Derivatives
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC01010E, CommunicationZongkang Wang, Yiting Liu, Chaoying Liang, Yihui Yan, Linrui Yang, Yan Wang, Yakun Jiang, Chengyu Wang, Yanzhong Li
We reported the first visible light-induced 6π electrocyclic reaction for the divergent synthesis of seven-membered ring derivatives. When BHT was employed, the indole skeletons bearing seven-membered rings underwent a 6π/4π...
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DOI: 10.1039/D6GC01010E, CommunicationZongkang Wang, Yiting Liu, Chaoying Liang, Yihui Yan, Linrui Yang, Yan Wang, Yakun Jiang, Chengyu Wang, Yanzhong Li
We reported the first visible light-induced 6π electrocyclic reaction for the divergent synthesis of seven-membered ring derivatives. When BHT was employed, the indole skeletons bearing seven-membered rings underwent a 6π/4π...
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Engineered Microbial Catalyst for Simultaneous Depolymerization and Upcycling of Polycaprolactone
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC00678G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Saint Moon Kim, Yoonjoo Seo, Renjing Jiang, Linrui Tan, Linduo Zhao, John W Scott, Yong-Su Jin, Na Wei
Plastic waste is a pressing global challenge. Although end-of-life plastics have long been regarded as an environmental burden, they also represent a vast yet underutilized carbon resource that could be...
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DOI: 10.1039/D6GC00678G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Saint Moon Kim, Yoonjoo Seo, Renjing Jiang, Linrui Tan, Linduo Zhao, John W Scott, Yong-Su Jin, Na WeiPlastic waste is a pressing global challenge. Although end-of-life plastics have long been regarded as an environmental burden, they also represent a vast yet underutilized carbon resource that could be...
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Organocatalytic electrochemical synthesis of α-quaternary amino aldehydes
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC01193D, CommunicationJun Tan, Yueyue Fan, Youai Qiu, Dengke Ma
α-Quaternary amino aldehydes are highly valuable synthetic targets in synthetic and medicinal chemistry, yet the efficient synthesis of sterically hindered α-quaternary amino aldehydes, especially for amino drug modification, remains a...
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DOI: 10.1039/D6GC01193D, CommunicationJun Tan, Yueyue Fan, Youai Qiu, Dengke Ma
α-Quaternary amino aldehydes are highly valuable synthetic targets in synthetic and medicinal chemistry, yet the efficient synthesis of sterically hindered α-quaternary amino aldehydes, especially for amino drug modification, remains a...
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Hydrogen Isotope Exchange of Multisubstituted Alkenes Catalyzed by Zeolite
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC00499G, PaperYuan Gao, Feiyu Qiu, Yi Chen, Huize Li, Andi Zou, Zhanhong Zheng, Xinhao Tang, Aiwen Lei, Wu Li
Olefins are widely present in natural products and synthetic drugs, and also serve as building blocks in organic synthesis. However, deuterated multisubstituted alkenes are rarely reported, owing to structural limitations...
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DOI: 10.1039/D6GC00499G, PaperYuan Gao, Feiyu Qiu, Yi Chen, Huize Li, Andi Zou, Zhanhong Zheng, Xinhao Tang, Aiwen Lei, Wu Li
Olefins are widely present in natural products and synthetic drugs, and also serve as building blocks in organic synthesis. However, deuterated multisubstituted alkenes are rarely reported, owing to structural limitations...
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Radical-mediated conversion of methane and water to light alcohols
DOI: 10.1039/D6GC01413E, CommunicationZeyu Gao, Di Li, Yuping Yang, Chenxin Wu, Li Wang, Zhaolun Cui, Lei Hua, Haiyang Li, Chong Peng, Dehui Deng, Yanhui Yi
This work offers valuable insights for green methane conversion, representing a significant advancement in process simplification and sustainability.
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Two-step sequential reactions involving supercritical CO2 and photocatalysis for PET degradation and hydrogen production
DOI: 10.1039/D6GC00641H, PaperYanbing Liu, Jinwen Shi, Zitong Zhuang, Xing Kang, Wenbo Xiao, Binjiang Zhai, Mengyuan Zhu, Hui Jin, Liejin Guo
This study combined supercritical CO2 and photocatalysis to hydrolyze plastic into monomers and converted them into valuable chemicals with simultaneous H2 production, achieving green upcycling of waste plastic under mild conditions.
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Recovery of silver from end-of-life silicon solar panels through a peroxymonosulfate-based advanced oxidation approach
DOI: 10.1039/D5GC06177F, PaperZhaoyi Yang, Longyan Chang, Weijun Zhang, Dongsheng Wang
In PMS/Fe2+, high-valent Fe(IV is generated, which converts PMS to singlet oxygen (1O2) and sulfate radicals (SO4˙−). These reactive species oxidize Ag0 to soluble Ag+, enabling rapid and efficient silver leaching from end-of-life silicon solar cells.
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Reclaiming carbon fibres: a green catalytic route for low-temperature CFRP recycling
DOI: 10.1039/D5GC06006K, CommunicationYunzi Xin, Mai Goto, Takashi Shirai
A green catalytic strategy enables low-temperature recycling of CFRP, selectively removing the resin matrix and recovering structurally preserved carbon fibres for sustainable reuse.
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Sustainability Impact for Extraction (SIX Score): from Concepts and Principles to Impact-based Metric for Green Extraction Assessment
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D5GC07041D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Giorgio Capaldi, CLELIA AIMONE, giorgio mongardi, Emanuela Calcio Gaudino, Giorgio Grillo, Giancarlo Cravotto
The shift towards a circular and sustainable economy has positioned the biorefinery sector as a key player in the valorisation of industrial by-products, particularly through the extraction of bioactive compounds...
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DOI: 10.1039/D5GC07041D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Giorgio Capaldi, CLELIA AIMONE, giorgio mongardi, Emanuela Calcio Gaudino, Giorgio Grillo, Giancarlo CravottoThe shift towards a circular and sustainable economy has positioned the biorefinery sector as a key player in the valorisation of industrial by-products, particularly through the extraction of bioactive compounds...
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Accurately regulating the Ni coordination environment via atomic layer deposition and enabling efficient CO2 electroreduction
DOI: 10.1039/D6GC01127F, PaperXian Liu, Shuangfeng Xing, Jijie Li, Wen-Yan Zan, Zhe Gao, Fengwei Zhang
The 5Ni@NC-400H catalyst with Ni2N6 sites showed 99.5% of FECO for CO2RR to CO at −0.77 V and FECO retained >99% from −0.37 to −1.17 V vs. RHE in flow cell. The CO2 activation at Ni2N6 sites occurs via bridging absorption of reaction intermediates.
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An emulsifier- and organic solvent-free one-step method for fabricating nano-encapsulated phase change materials
DOI: 10.1039/D6GC00361C, PaperJiayi Liu, Jiao Wu, Linbo Guan, Zhonghua Wang, Yulong Xiao, Xiaowei Fu, Liang Jiang, Jingxin Lei, Yuan Lei, Yao Xiao
An emulsifier- and organic solvent-free one-step method is introduced for the fabrication of NePCMs. The resulting NePCM exhibited a unique interpenetrating core–shell structure, and demonstrated a high encapsulation efficiency of 96.3%.
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