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A novel and sustainable continuous-flow approach for atom deletion and insertion by electrophilic nitrogen transfer
DOI: 10.1039/D6GC01875K, Paper
Open Access 
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Niamh Disney, Laura Marraffa, Mert Can Ince, Philipp Natho, Marco Colella, Gianvito Vilé, Marcus Baumann, Renzo LuisiA unified continuous-flow protocol for electrophilic nitrogen transfer enables skeletal editing via N-insertion, deletion, nitrile formation and aziridination, with sustainability validated through life cycle assessment and techno-economic analysis.
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Concise chemical synthesis of O-linked glycans
DOI: 10.1039/D6GC01945E, PaperYaohao Li, Wenqiang Liu, Chunyu Jin, Huanjie Zhu, Zerun Song, Jiongkun Peng, Chong Guo, Zhongping Tan
A concise divergent strategy affords 10 core-1 type O-linked glycoamino acid building blocks. Their availability enables homogeneous GHRH glycoform preparation and reveals that Thr7 O-glycosylation improves proteolytic stability against DPP-IV.
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